Product ID:STATE LUB
MSDS Date:10/01/1986
FSC:9150
NIIN:00N051309
MSDS Number: BTZPS

STATE CHEMICAL MFG CO

3100 HAMILTON AVE
CLEVELAND, OH 44114
US

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE) (SARA

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: <30%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM;450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHANE, 1,1,2-TRICHLORO-1,2,2-TRIFLUORO-;

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: <65%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM;1250 STEL

(TRICHLOROTRIFLUOROETHANE) (FREON 113) (SARA III)

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

PROPANE (PROPELLANT)

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: <16%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PROLONGED EXPOSURE TO VAPORS MAY
RESULT IN HEADACHE, DROWSINESS OR IRRITATION OF EYES & NOSE. DIRECT
CONTACT W/EYES OR SKIN MAY RESULT IN IRRITATION, ESPECIALLY IF SKIN
IS BROKEN. DO NOT TAKE INTERNAL LY. CHLOROFLUOROCARBON (CFC) &
CHLOROCARBON MATERIALS HAVE PRODUCED SENSITIZATION OF MYOCARDIUM TO
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:EPINEPHRINE IN LAB ANIMALS & COULD
HAVE SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (I.E., EPINEPHRINE)
MAY BE CONTRA-INDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS
ACUTELY OR CHRONICALLY E XPOSED TO CHLOROCARBONS OR CFC'S .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15
MINUTES, SEEK ASSISTANCE FROM MD . INGEST:DO NOT INDUCE VOMITING.
CALL MD. INHAL:REMOVE PERSON TO FRESH AIR. IF IRRITATION PERSISTS,
CA LL MD. SKIN:WASH THOROUGHLY W/SOAP & WATER. IF IRRITATION
PERSISTS, CALL MD.

Flash Point:SUPP DATA
Extinguishing Media:WATERFOG, FOAM, CO*2 OR DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD PRESS DEMAND SCBA & FULL
PROT EQUIP . KEEP CONTAINERS COOL. USE SHIELDING TO PROTECT PERS
FROM RUPTURING, VENTING/BURSTING CNTNRS.
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCL FLUORIDES,
CHLORIDES & PHOSGENE . EXPOSURE TO TEMPS >120F MAY CAUSE CANS TO
VENT, RUPTURE OR BURST.

Spill Release Procedures:REMOVE SOURCES OF HEAT, FLAME OR SPARKS.
VENTILATE THE AREA. ABSORB SPILL USING STATE OIL ABSORBENT, SAND OR
VERMICULITE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CONTENTS UNDER PRESS. DO NOT STORE IN
DIRECT SUNLIGHT, NEAR SPKS/FLAME OR WHERE TEMPS MAY EXCEED 120F.
VAP MAY BE HARMFUL. AVOID CONT W/EYES OR SKIN.
Other Precautions:AVOID PRLNG/RPTD BRTHG OF VAPS. DO NOT TAKE
INTERNALLY. DO NOT USE ON/NEAR BROKEN SKIN. READ & FOLLOW ALL LBL
DIRECTIONS & PRECS BEFORE USING PROD. THESE PRODS ARE INTENDED FOR
INDUS USE ONLY. KEEP OU T OF REACH OF CHILDREN. NO (SUPP DATA)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . DO NOT BREATHE CONCENTRATED VAPORS OF THIS
PRODUCT.
Ventilation:ALWAYS USE W/ADEQUATE VENTILATION.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:NONE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
% VOLAT:>90(WT). FL PT:NO FLAME PROJECTION. HAZ DECOMP PROD:GASES SUCH
AS HCL/HF. OTHER PREC:SMOKING IN AREA OF USE. DO NOT USE IN GEN
VICIN OF ARC WELDING, OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIA M
AY CAUSE FORM OF CHLORIDE, FLUORIDES/PHOSGENE .

Solubility in Water:<1%
Appearance and Odor:CLEAR AEROSOL SPRAY W/CHLORINATED ODOR.
Percent Volatiles by Volume:SUPDAT

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, STRONG CAUSTICS, ACTIVE LIGHT METALS, ESP MAGNESIUM.
THIS PRODUCT MAY ATTACK SOME PLASTICS.
Stability Condition to Avoid:EXPOSURE TO TEMPERATURES >120F.
Hazardous Decomposition Products:FLUORIDES, CHLORIDES & PHOSGENE .
BURNING THIS PROD MAY RSLT IN FORM OF CARBON MONOXIDE & TOX
HALOGENATED (SUPDAT)

Waste Disposal Methods:FOLLOW ALL FEDERAL, STATE & LOCAL REGULATIONS
REGARDING WASTE DISPOSAL. DO NOT PUNCTURE OR INCINERATE CANS. GIVE
CANS TO A DISPOSAL SERVICE EQUIPPED TO SAFETLY HANDLE & DISPOSE OF
PRESSURIZED CONTAINE RS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.